The Birth of Arale
Main article: Volume 1: The Birth of Arale
In Bearly Friends!, He shoots down the Bear that Arale Norimaki released back into the wild and was thrown far away by Arale who got mad at him for it. Both him and his assistant landed in a place where they were surrounded by lions.
The Indestructible Caramel Man 007!
Main article: Volume 14: The Indestructible Caramel Man 007!
In Gatchan You're Great!!, the anime adaptation of Way to go, Gatchan!!!, the hunter and his assistant are shown to be the ones that injured the Gorilla while trying to hunt him. The Gatchan's both zap the hunter and punch the assistant into a tree launching him away.
- The Hunter is the first villain to actually get Arale angry.